Dichothermal layer deepening in relation with halocline depth change associated with northward shrinkage of North Pacific western subarctic gyre in early 2000s     

Akira Nagano  Masahide Wakita  Shuichi Watanabe 《Ocean Dynamics》2016,66(2):163-172

In the western subarctic North Pacific, a wind-driven cyclonic circulation, called the western subarctic gyre (WSAG), exists. We examined year-to-year changes of the gyre and hydrographic structures, applying the altimetry-based gravest empirical mode (AGEM) method to hydrographic and altimetric sea surface height (SSH) data, and relation to the in situ variation of the temperature minimum layer, i.e., the dichothermal layer, depth at station K2 (47^° N, 160^° E). The AGEM-based geostrophic volume transport and the streamfunction of the WSAG in the top 1000-dbar layer show that the gyre changes substantially. From the late 1990s to the mid-2000s, the gyre shrunk northward. Due to the shrinkage, the halocline bottom, which is equivalent to the top of the main pycnocline, deepens at K2 outside the central part of the gyre. The downward displacement of the dichothermal layer at K2 was found to be significantly related to that of the underlying halocline due to the northward shrinkage of the WSAG.  相似文献   

Comparison of carbon cycle between the western Pacific subarctic and subtropical time-series stations: highlights of the K2S1 project     

Makio C. Honda  Masahide Wakita  Kazuhiko Matsumoto  Tetsuichi Fujiki  Eko Siswanto  Kosei Sasaoka  Hajime Kawakami  Yoshihisa Mino  Chiho Sukigara  Minoru Kitamura  Yoshikazu Sasai  Sherwood L. Smith  Taketo Hashioka  Chisato Yoshikawa  Katsunori Kimoto  Shuichi Watanabe  Toru Kobari  Toshi Nagata  Koji Hamasaki  Ryo Kaneko  Mario Uchimiya  Hideki Fukuda  Osamu Abe  Toshiro Saino 《Journal of Oceanography》2017,73(5):647-667

A comparative study of ecosystems and biogeochemistry at time-series stations in the subarctic gyre (K2) and subtropical region (S1) of the western North Pacific Ocean (K2S1 project) was conducted between 2010 and 2013 to collect essential data about the ecosystem and biological pump in each area and to provide a baseline of information for predicting changes in biologically mediated material cycles in the future. From seasonal chemical and biological observations, general oceanographic settings were verified and annual carbon budgets at both stations were determined. Annual mean of phytoplankton biomass and primary productivity at the oligotrophic station S1 were comparable to that at the eutrophic station K2. Based on chemical/physical observations and numerical simulations, the likely “missing nutrient source” was suggested to include regeneration, meso-scale eddy driven upwelling, meteorological events, and eolian inputs in addition to winter vertical mixing. Time-series observation of carbonate chemistry revealed that ocean acidification (OA) was ongoing at both stations, and that the rate of OA was faster at S1 than at K2 although OA at K2 is more critical for calcifying organisms.  相似文献   

Distribution of Fe among octahedral sites and its effect on the crystal structure of pumpellyite     

Mariko Nagashima  Takahiro Ishida  Masahide Akasaka 《Physics and Chemistry of Minerals》2006,33(3):178-191

Two pumpellyites with the general formula W ₈ X ₄ Y ₈ Z ₁₂O_56-n (OH) _n were studied using ⁵⁷Fe Mössbauer spectroscopic and X-ray Rietveld methods to investigate the relationship between the crystal chemical behavior of iron and structural change. The samples are ferrian pumpellyite-(Al) collected from Mitsu and Kouragahana, Shimane Peninsula, Japan. Rietveld refinements gave Fe(X):Fe(Y) ratios (%) of 41.5(4):58.5(4) for the Mitsu pumpellyite and 46(1):54(1) for the Kouragahana pumpellyite, where Fe(X) and Fe(Y) represent Fe content at the X and Y sites, respectively. The Mössbauer spectra consisted of two Fe²⁺ and two Fe³⁺ doublets for the Mitsu pumpellyite, and one Fe²⁺ and two Fe³⁺ doublets for the Kouragahana pumpellyite. In terms of the area ratios of the Mössbauer doublets and the Fe(X):Fe(Y) ratios determined by the Rietveld refinements, Fe²⁺(X):Fe³⁺(X):Fe³⁺(Y) ratios are determined to be 22:14:64 for the Mitsu pumpellyite and 27:8:65 for the Kouragahana pumpellyite. By applying the Fe²⁺:Fe³⁺-ratio determined by the Mössbauer analysis and the site occupancies of Fe at the X and Y sites given by the Rietveld method together with chemical analysis, the resulting formula of the Mitsu and Kouragahana pumpellyites are established as Ca₈(Fe _0.88 ²⁺ Mg_0.68Fe _0.77 ³⁺ Al_1.66)_Σ3.99(Al_5.67Fe _2.34 ³⁺ )_Σ8.01Si₁₂O_42.41(OH)_13.59 and Ca₈(Mg_1.24Fe _0.65 ²⁺ Fe _0.46 ³⁺ Al_1.66)_Σ4.01(Al_6.71Fe _1.29 ³⁺ )_Σ8.00Si₁₂O_42.14(OH)_13.86, respectively. Mean Y–O distances and volumes of the YO₆ octahedra increase with increasing mean ionic radii, i.e., the Fe³⁺→Al substitution at the Y site. However, change of the sizes of XO₆ octahedra against the mean ionic radii at the X site is not distinct, and tends to depend on the volume change of the YO₆ octahedra. Thus, the geometrical change of the YO₆ octahedra with Fe³⁺→Al substitution at the Y site is essential for the structural changes of pumpellyite. The expansion of the YO₆ octahedra by the ionic substitution of Fe³⁺ for Al causes gradual change of the octahedra to more symmetrical and regular forms.  相似文献   

Quartz dissolution experiments at various pH, temperature and stress conditions: CLSM and ICP-AES investigations     

Jung Hae Choi  Kazushi Kimoto  Yasuaki Ichikawa 《Environmental Earth Sciences》2012,66(8):2431-2440

To understand the effects of temperature, pH and mechanical stress on the pressure dissolution of quartz, two experiments using monocrystalline quartz samples were conducted. The first was a closed-fluid experiment to investigate the effect of pH, and the second was a flow-through experiment to investigate stress and temperature effects. To initiate the pressure dissolution, a pair of samples was immersed in a solution with a prescribed pH. The samples were stressed mechanically by pressing one sample against the other. In the closed-fluid experiments, the pH of the solution was fixed to 7, 9, 11 and 13, the applied stress was approximately 200 MPa and temperature 25°C. The flow-through experiments were conducted at three different temperatures (35, 50 and 75°C) at the same pH 11.7. The value of the applied stress was 7.32, 13.72, 21.42 or 25.27 MPa. During each of these dissolution tests, the solution was regularly sampled and analyzed by an Inductively Coupled Plasma-Atomic Emission Spectrometry technique to measure Si-concentration. With the measured Si-concentration, a dissolution rate constant was computed the different pH, stress and temperature conditions. The rate constant is proportional to pH, stress and temperature, as indicated in the literature. It should be noted that the rate constant for the highest stress (200 MPa) was considerably greater than for the other cases. In addition, island-channel patterns characterized by micro-cracks a few nanometers in length were seen on the dissolved parts of the samples. The findings and the measured data in this paper may be useful for the future development of theoretical models for pressure dissolution and its validation.  相似文献   

Sedimentary organic matter contents and porewater chemistry at upper bathyal depths influenced by the 2011 off the Pacific coast of Tohoku Earthquake and tsunami     

Hidetaka Nomaki  Kazuno Arai  Hisami Suga  Takashi Toyofuku  Masahide Wakita  Takuro Nunoura  Kazumasa Oguri  Takafumi Kasaya  Shuichi Watanabe 《Journal of Oceanography》2016,72(1):99-111

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Structural variation of babingtonite depending on cation distribution at the octahedral sites     

Mariko Nagashima  Keiko Mitani  Masahide Akasaka 《Mineralogy and Petrology》2014,108(2):287-301

Babingtonite, Ca₂Fe²⁺Fe³⁺[Si₅O₁₄(OH)] (Z?=?2, space group $ P\overline{1} $ ) from Yakuki mine (Japan), Grönsjöberget (Sweden), Kandivali Quarry (India), Baveno Quarry (Italy), Bråstad Mine (Norway), and Kouragahana (Japan), and manganbabingtonite, Ca₂(Mn²⁺, Fe²⁺)Fe³⁺[Si₅O₁₄(OH)], from Iron Cap mine (USA) were studied using electron-microprobe analysis (EMPA), ⁵⁷Fe Mössbauer analysis and single-crystal X-ray diffraction methods to determine the cation distribution at M1 and M2 and to analyze its effect on the crystal structure of babingtonite. Although all studied babingtonite crystals are relatively homogeneous, chemical zonation due to mainly Fe ? Mn substitution is observed in manganbabingtonite. Mössbauer spectra consist of two doublets with isomer shift (I.S.)?=?1.16–1.22 mm/s and quadrupole splitting (Q.S.)?=?2.33–2.50 mm/s and with I.S.?=?0.38–0.42 mm/s and Q.S.?=?0.82–0.90 mm/s, assigned to Fe²⁺ and Fe³⁺ at the M1 and M2 octahedral sites, respectively. The determined ratio of Fe²⁺/total Fe in manganbabingtonite (0.26) was smaller than that in the others (0.35–0.44) because of high Mn²⁺ content instead of Fe²⁺. The unit-cell parameters of babingtonite are a?=?7.466–7.478, b?=?11.624–11.642, c?=?6.681–6.690 Å, α?=?91.53–91.59, β?=?93.86–93.94, γ?=?104.20–104.34º, and V?=?560.2–562.3 Å³, and those of manganbabingtonite are a?=?7.4967(3), b?=?11.6632(4), c?=?6.7014(2) Å, α?=?91.602(2), β?=?93.989(2), γ?=?104.574(3)º, and V =565.09(5) ų. Structural refinements converged to R ₁ values of 1.64–3.16 %. The <M1-O> distance was lengthened due to the substitution of large octahedral cations such as Mn²⁺ for Fe²⁺. The increase of the M1-O8, M1-O8’ and M1-O13 lengths with mean ionic radii is slightly more pronounced than of the other M1-Oi lengths. The lengthened M1-O13 distance leads the positive correlation between Si5-O15-Si1 angle and M1-O13 distance. The increase of Si2-O3-Si1 and Si5-O12-Si4 angles due to the increase of mean ionic radius of M2 is also observed.  相似文献   

Upper ocean warming pattern in the past 50 years     

Sayaka Yasunaka  Masahide Kimoto 《Journal of Oceanography》2013,69(1):87-95

A long-term warming pattern of global subsurface ocean was detected separately from other natural variations. Three dominant modes were extracted: a long-term warming mode, a mode related to the El Niño/Southern Oscillation, and a mode related to the Atlantic Multidecadal Oscillation. The long-term warming mode explained 78 % of the global mean temperature variance from the surface to a depth of 300 m, and the other two modes could explain most of the residual variance. Subsurface warming associated with the long-term warming mode was strong in the subtropics. In contrast, there was a local minimum of warming in the northern hemisphere subarctic ocean, and warming was suppressed in subsurface waters south of the equator. Atmospheric changes associated with the long-term warming mode showed negative (positive) sea level pressure anomalies at high (middle) latitudes in both hemispheres, and an intensification and/or a poleward expansion of mid-latitude westerlies. Wind stress curl changes were negative in the subtropics and positive in the subarctic of the northern hemisphere; changes that were consistent with the strong warming in the subtropics and the local minimum of warming in the subarctic. Warming of Southern Ocean subsurface waters coincided with southward migration and intensification of westerly winds, whereas surface warming to the south of 50°S was suppressed, probably by strengthened northward Ekman transport. Positive wind stress curl off the equator with weakening of the tropical easterly winds in the Pacific and Indian Oceans was consistent with the subsurface negative temperature anomaly there.  相似文献   

Distribution and photo-physiological condition of phytoplankton in the tropical and subtropical North Pacific     

Tetsuichi Fujiki  Kazuhiko Matsumoto  Toshiro Saino  Masahide Wakita  Shuichi Watanabe 《Journal of Oceanography》2013,69(1):35-43

To better understand the vertical distribution of phytoplankton in the tropical and subtropical North Pacific, we used fast repetition rate fluorometry to investigate the photo-physiological condition of the phytoplankton assemblage in this region between February and March 2007. Along 155°E, between the equator and 24°N, the peak of fluorescence (F _m), an indication of the deep chlorophyll maximum (DCM), was deeper than the top of the nitracline and occurred at the 2.4 ± 1.3 % (mean ± SD) light depth (relative to 0 m). The photochemical efficiency (F _v/F _m) and effective absorption cross-section of photosystem II (σ_PSII) were low at the surface but increased rapidly at depths between the top of the nitracline (40–138 m) and the DCM (70–158 m), an indication that the photo-physiological condition of the phytoplankton improved below the top of the nitracline. The depth of the maximal F _v/F _m [Z(F _v/F _{m max})] was 18–32 m deeper than the DCM and corresponded to the 0.8 ± 0.2 % light depth. The values of F _v/F _m at the Z(F _v/F _{m max}) were 20 % higher than those at the DCM and averaged 0.48 ± 0.01. These results suggest that the phytoplankton assemblage beneath the DCM had a high potential photosynthetic performance capacity and was growing by using the very low ambient light in this region.  相似文献